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Issue 69, 2016
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Selection of two optional covalent bonds by electric stimuli: dual catalytic switching of redox-active copper

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Abstract

Two types of redox functionality were selected for covalent immobilization on a carbon electrode, using an electric potential as the sole stimulus. A redox-active copper catalyst transformed a terminal alkyne in two ways with and without an oxidation process, to form a triazole or butadiyne.

Graphical abstract: Selection of two optional covalent bonds by electric stimuli: dual catalytic switching of redox-active copper

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Supplementary files

Article information


Submitted
23 Apr 2016
Accepted
13 Jul 2016
First published
14 Jul 2016

Chem. Commun., 2016,52, 10486-10489
Article type
Communication
Author version available

Selection of two optional covalent bonds by electric stimuli: dual catalytic switching of redox-active copper

Y. Kamamoto, Y. Nitta, K. Kubo, T. Mizuta and S. Kume, Chem. Commun., 2016, 52, 10486 DOI: 10.1039/C6CC03407A

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