With the help of theoretical predictions, we have found, from the [donor–metal–acceptor] system, the first photochromic pyrazine-based compound that can undergo photoinduced charge separation and yield stable pyrazine radicals.
X. Zhang, M. Wang, C. Sun, C. Yang, P. Li and G. Guo, Chem. Commun., 2016, 52, 7947 DOI: 10.1039/C6CC03354G
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