Issue 44, 2016

Immobilization of ionic liquids to covalent organic frameworks for catalyzing the formylation of amines with CO2 and phenylsilane

Abstract

We presented the immobilization of ionic liquids on the channel walls of COFs using a post-synthetic strategy. The ionic [Et4NBr]50%-Py-COF afforded a high CO2 adsorption capacity of 164.6 mg g−1 (1 bar, 273 K) and was developed as an effective heterogeneous catalyst for the transformation of CO2 into value-added formamides under ambient conditions.

Graphical abstract: Immobilization of ionic liquids to covalent organic frameworks for catalyzing the formylation of amines with CO2 and phenylsilane

Supplementary files

Article information

Article type
Communication
Submitted
12 Apr 2016
Accepted
28 Apr 2016
First published
28 Apr 2016

Chem. Commun., 2016,52, 7082-7085

Immobilization of ionic liquids to covalent organic frameworks for catalyzing the formylation of amines with CO2 and phenylsilane

B. Dong, L. Wang, S. Zhao, R. Ge, X. Song, Y. Wang and Y. Gao, Chem. Commun., 2016, 52, 7082 DOI: 10.1039/C6CC03058K

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