Issue 47, 2016
From the journal:

Chemical Communications

(−)/(+)-Sparteine induced chirally-active carbon nanoparticles for enantioselective separation of racemic mixtures†

Gururaja Vulugundam,‡a   Santosh K. Misra,‡a   Fatemeh Ostadhossein,a   Aaron S. Schwartz-Duval,a   Enrique A. Dazaa  and  Dipanjan Pan*a  

* Corresponding authors

a Department of Bioengineering, Beckman Institute, Materials Science and Engineering, University of Illinois at Urbana-Champaign, 502 N. Busey, Urbana, IL, USA
E-mail: dipanjan@illinois.edu

Abstract

Chiral carbon nanoparticles (CCNPs) were developed by surface passivation using the chiral ligand (−)-sparteine or (+)-sparteine (denoted (−)-SP/CNP and (+)-SP/CNP, respectively). The chirality of the prepared CCNPs was demonstrated by circular dichroism and polarimetry and employed as an enantioselective separation platform for representative racemic mixtures.

Graphical abstract: (−)/(+)-Sparteine induced chirally-active carbon nanoparticles for enantioselective separation of racemic mixtures

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Article information

DOI
https://doi.org/10.1039/C6CC02525K
Article type
Communication
Submitted
24 Mar 2016
Accepted
16 May 2016
First published
16 May 2016

Chem. Commun., 2016,52, 7513-7516

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(−)/(+)-Sparteine induced chirally-active carbon nanoparticles for enantioselective separation of racemic mixtures

G. Vulugundam, S. K. Misra, F. Ostadhossein, A. S. Schwartz-Duval, E. A. Daza and D. Pan, Chem. Commun., 2016, 52, 7513 DOI: 10.1039/C6CC02525K

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