Issue 41, 2016
From the journal:

Chemical Communications

Iron-catalyzed domino indole fluorination/allenic aza-Claisen rearrangement†

Benito Alcaide,*a   Pedro Almendros,*b   Sara Cembellín,a   Teresa Martínez del Campo*a  and  Alejandro Muñoza  

* Corresponding authors

a Grupo de Lactamas y Heterociclos Bioactivos, Departamento de Química Orgánica, Unidad Asociada al CSIC, Facultad de Química, Universidad Complutense de Madrid, 28040-Madrid, Spain
E-mail: alcaideb@quim.ucm.es
Fax: +34 91-3944103

b Instituto de Química Orgánica General, IQOG-CSIC, Juan de la Cierva 3, 28006-Madrid, Spain
E-mail: Palmendros@iqog.csic.es
Fax: +34 91-5644853

Abstract

The synthesis of 2-allenyl-2-substituted-3,3-difluoroindolines has been accomplished, taking advantage of the reaction between N-allenyl-indoles and Selectfluor under iron catalysis.

Graphical abstract: Iron-catalyzed domino indole fluorination/allenic aza-Claisen rearrangement

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Article information

DOI
https://doi.org/10.1039/C6CC02012G
Article type
Communication
Submitted
07 Mar 2016
Accepted
21 Apr 2016
First published
21 Apr 2016

Chem. Commun., 2016,52, 6813-6816

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Iron-catalyzed domino indole fluorination/allenic aza-Claisen rearrangement

B. Alcaide, P. Almendros, S. Cembellín, T. Martínez del Campo and A. Muñoz, Chem. Commun., 2016, 52, 6813 DOI: 10.1039/C6CC02012G

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