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Issue 35, 2016
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A bifunctional chiral [2]catenane based on 1,1′-binaphthyl-phosphates

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Abstract

A novel [2]catenane was synthesised by ring-closing metathesis from a Ca-bisphosphate template. The resulting interlocked structure features two chiral 1,1′-binaphthyl-phosphates, leading to a bifunctional catenane structure. Initial binding studies point at the applicability of such mechanically interlocked bisphosphates as artificial receptors for dicationic guest molecules.

Graphical abstract: A bifunctional chiral [2]catenane based on 1,1′-binaphthyl-phosphates

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Publication details

The article was received on 05 Mar 2016, accepted on 29 Mar 2016 and first published on 29 Mar 2016


Article type: Communication
DOI: 10.1039/C6CC01980C
Chem. Commun., 2016,52, 5977-5980
  • Open access: Creative Commons BY-NC license
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    A bifunctional chiral [2]catenane based on 1,1′-binaphthyl-phosphates

    R. Mitra, M. Thiele, F. Octa-Smolin, M. C. Letzel and J. Niemeyer, Chem. Commun., 2016, 52, 5977
    DOI: 10.1039/C6CC01980C

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