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Issue 35, 2016
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Formation of a unique ‘unsupported’ hydridic stannate(ii)

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The reaction of the amido-stannate LiSn(NMe2)3 with the phosphine–borane tBu2PHBH3 gives the SnII hydride [(Me2NH)2Li{BH3P(tBu)2}2Sn(H)]; the first example of a hydridic stannate(II) that is not supported by transition metal or ligand bonding.

Graphical abstract: Formation of a unique ‘unsupported’ hydridic stannate(ii)

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The article was received on 02 Mar 2016, accepted on 04 Apr 2016 and first published on 04 Apr 2016

Article type: Communication
DOI: 10.1039/C6CC01885H
Chem. Commun., 2016,52, 5993-5996

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    Formation of a unique ‘unsupported’ hydridic stannate(II)

    M. Fernández-Millán, L. K. Allen, R. García-Rodríguez, A. D. Bond, M. E. G. Mosquera and D. S. Wright, Chem. Commun., 2016, 52, 5993
    DOI: 10.1039/C6CC01885H

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