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Issue 28, 2016
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Bi(III) polybromides: a new chapter in coordination chemistry of bismuth

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Abstract

A new family of bismuth coordination compounds – Bi(III) polybromides – is introduced. Four representatives of this class – (N-EtPy)3[Bi2Br9](Br2)2 (1), (4-MePyH)3[Bi2Br9](Br2) (2), (H2bpe){[BiBr5]}(Br2) (3) and (BPB)2[BiBr5(Br3)](Br3)(Br2) (4) – were obtained in a simple way from HBr solutions of BiBr3 with added Br2, highlighting the diversity of the structural types in the new family of complexes.

Graphical abstract: Bi(iii) polybromides: a new chapter in coordination chemistry of bismuth

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Publication details

The article was received on 25 Feb 2016, accepted on 10 Mar 2016 and first published on 10 Mar 2016


Article type: Communication
DOI: 10.1039/C6CC01704E
Citation: Chem. Commun., 2016,52, 5061-5063
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    Bi(III) polybromides: a new chapter in coordination chemistry of bismuth

    S. A. Adonin, I. D. Gorokh, D. G. Samsonenko, M. N. Sokolov and V. P. Fedin, Chem. Commun., 2016, 52, 5061
    DOI: 10.1039/C6CC01704E

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