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Issue 40, 2016
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Olefin hydrosilylation catalyzed by cationic nickel(ii) allyl complexes: a non-innocent allyl ligand-assisted mechanism

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Abstract

The arene-supported cationic nickel allyl complexes serve as good catalysts for olefin hydrosilylation at room temperature. Detailed mechanistic studies based on experiments and DFT calculations support the novel mechanism, which includes the facile Si–H bond cleavage and Si–C bond formation, assisted by a non-innocent allyl ligand.

Graphical abstract: Olefin hydrosilylation catalyzed by cationic nickel(ii) allyl complexes: a non-innocent allyl ligand-assisted mechanism

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Article information


Submitted
25 Feb 2016
Accepted
11 Apr 2016
First published
12 Apr 2016

Chem. Commun., 2016,52, 6723-6726
Article type
Communication

Olefin hydrosilylation catalyzed by cationic nickel(II) allyl complexes: a non-innocent allyl ligand-assisted mechanism

J. Mathew, Y. Nakajima, Y.-K. Choe, Y. Urabe, W. Ando, K. Sato and S. Shimada, Chem. Commun., 2016, 52, 6723
DOI: 10.1039/C6CC01665K

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