Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 40, 2016
Previous Article Next Article

Olefin hydrosilylation catalyzed by cationic nickel(II) allyl complexes: a non-innocent allyl ligand-assisted mechanism

Author affiliations

Abstract

The arene-supported cationic nickel allyl complexes serve as good catalysts for olefin hydrosilylation at room temperature. Detailed mechanistic studies based on experiments and DFT calculations support the novel mechanism, which includes the facile Si–H bond cleavage and Si–C bond formation, assisted by a non-innocent allyl ligand.

Graphical abstract: Olefin hydrosilylation catalyzed by cationic nickel(ii) allyl complexes: a non-innocent allyl ligand-assisted mechanism

Back to tab navigation

Supplementary files

Publication details

The article was received on 25 Feb 2016, accepted on 11 Apr 2016 and first published on 12 Apr 2016


Article type: Communication
DOI: 10.1039/C6CC01665K
Citation: Chem. Commun., 2016,52, 6723-6726

  •   Request permissions

    Olefin hydrosilylation catalyzed by cationic nickel(II) allyl complexes: a non-innocent allyl ligand-assisted mechanism

    J. Mathew, Y. Nakajima, Y.-K. Choe, Y. Urabe, W. Ando, K. Sato and S. Shimada, Chem. Commun., 2016, 52, 6723
    DOI: 10.1039/C6CC01665K

Search articles by author

Spotlight

Advertisements