〈100〉-oriented Pt and Pt–Rh supercrystals were directly synthesized in N,N-dimethylformamide (DMF) solution. DMF was demonstrated to serve as the facet-specific agent of the (100) facets and the driving force for the self-assembly of Pt and Pt–Rh building blocks due to the strong bonding interaction between metal atoms on the (100) facets and the carbonyl group of DMF.
L. Dai, X. Wang, X. Zheng and Y. Zhang, Chem. Commun., 2016, 52, 5023 DOI: 10.1039/C6CC01110A
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