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Issue 32, 2016
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Halogen bonding between metal centers and halocarbons

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Abstract

Metal-involving halogen bonding was detected in a series of associates of CHI3 with trans-[PtX2(NCNAlk2)2] (X = Cl, Br). The HI2C–I⋯η1(Pt) halogen bonding and the bifurcated HI2C–I⋯η2(Pt–Cl) halogen bonding – the latter undergoes the thermally induced reversible HI2C–I⋯η2(Pt–Cl) ⇄ HI2C–I⋯η1(Pt) transformation – were observed and confirmed theoretically.

Graphical abstract: Halogen bonding between metal centers and halocarbons

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Supplementary files

Article information


Submitted
03 Feb 2016
Accepted
16 Mar 2016
First published
16 Mar 2016

This article is Open Access

Chem. Commun., 2016,52, 5565-5568
Article type
Communication

Halogen bonding between metal centers and halocarbons

D. M. Ivanov, A. S. Novikov, I. V. Ananyev, Y. V. Kirina and V. Yu. Kukushkin, Chem. Commun., 2016, 52, 5565
DOI: 10.1039/C6CC01107A

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