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Issue 32, 2016
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Halogen bonding between metal centers and halocarbons

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Abstract

Metal-involving halogen bonding was detected in a series of associates of CHI3 with trans-[PtX2(NCNAlk2)2] (X = Cl, Br). The HI2C–I⋯η1(Pt) halogen bonding and the bifurcated HI2C–I⋯η2(Pt–Cl) halogen bonding – the latter undergoes the thermally induced reversible HI2C–I⋯η2(Pt–Cl) ⇄ HI2C–I⋯η1(Pt) transformation – were observed and confirmed theoretically.

Graphical abstract: Halogen bonding between metal centers and halocarbons

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Publication details

The article was received on 03 Feb 2016, accepted on 16 Mar 2016 and first published on 16 Mar 2016


Article type: Communication
DOI: 10.1039/C6CC01107A
Chem. Commun., 2016,52, 5565-5568
  • Open access: Creative Commons BY-NC license
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    Halogen bonding between metal centers and halocarbons

    D. M. Ivanov, A. S. Novikov, I. V. Ananyev, Y. V. Kirina and V. Yu. Kukushkin, Chem. Commun., 2016, 52, 5565
    DOI: 10.1039/C6CC01107A

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