Issue 32, 2016

Halogen bonding between metal centers and halocarbons

Abstract

Metal-involving halogen bonding was detected in a series of associates of CHI3 with trans-[PtX2(NCNAlk2)2] (X = Cl, Br). The HI2C–I⋯η1(Pt) halogen bonding and the bifurcated HI2C–I⋯η2(Pt–Cl) halogen bonding – the latter undergoes the thermally induced reversible HI2C–I⋯η2(Pt–Cl) ⇄ HI2C–I⋯η1(Pt) transformation – were observed and confirmed theoretically.

Graphical abstract: Halogen bonding between metal centers and halocarbons

Supplementary files

Article information

Article type
Communication
Submitted
03 Feb 2016
Accepted
16 Mar 2016
First published
16 Mar 2016
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2016,52, 5565-5568

Halogen bonding between metal centers and halocarbons

D. M. Ivanov, A. S. Novikov, I. V. Ananyev, Y. V. Kirina and V. Yu. Kukushkin, Chem. Commun., 2016, 52, 5565 DOI: 10.1039/C6CC01107A

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