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Issue 30, 2016
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Insights into the effect of surface ligands on the optical properties of thiolated Au25 nanoclusters

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Abstract

An abnormal optical absorption at about 780 and 980 nm was observed for Au25 nanoclusters (NCs) protected by negatively charged thiolate ligands collocating with positively or neutrally charged thiolate ligands, largely due to the resultant surface charge anisotropy on the NC surface which could induce structural distortions of the thiolated Au25 NCs.

Graphical abstract: Insights into the effect of surface ligands on the optical properties of thiolated Au25 nanoclusters

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Supplementary files

Article information


Submitted
28 Jan 2016
Accepted
23 Feb 2016
First published
24 Feb 2016

Chem. Commun., 2016,52, 5234-5237
Article type
Communication

Insights into the effect of surface ligands on the optical properties of thiolated Au25 nanoclusters

X. Yuan, N. Goswami, W. Chen, Q. Yao and J. Xie, Chem. Commun., 2016, 52, 5234
DOI: 10.1039/C6CC00857G

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