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Issue 58, 2016
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Cyclopentadiene-mediated hydride transfer from rhodium complexes

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Abstract

Attempts to generate a proposed rhodium hydride catalytic intermediate instead resulted in isolation of (Cp*H)Rh(bpy)Cl (1), a pentamethylcyclopentadiene complex, formed by C–H bond-forming reductive elimination from the fleeting rhodium hydride. The hydride transfer ability of diene 1 was explored through thermochemistry and hydride transfer reactions, including the reduction of NAD+.

Graphical abstract: Cyclopentadiene-mediated hydride transfer from rhodium complexes

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Publication details

The article was received on 20 Jan 2016, accepted on 29 Feb 2016 and first published on 01 Mar 2016


Article type: Communication
DOI: 10.1039/C6CC00575F
Chem. Commun., 2016,52, 9105-9108
  • Open access: Creative Commons BY-NC license
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    Cyclopentadiene-mediated hydride transfer from rhodium complexes

    C. L. Pitman, O. N. L. Finster and A. J. M. Miller, Chem. Commun., 2016, 52, 9105
    DOI: 10.1039/C6CC00575F

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