Representative benzylic, allylic and α-keto alcohols are deoxygenated to alkanes and/or reductively coupled to alkane dimers by reaction with PPh3 catalyzed by (PPh3)2ReIO2 (1). The newly discovered catalytic reductive coupling reaction is a rare C–C bond-forming transformation of alcohols.
G. R. Kasner, C. Boucher-Jacobs, J. Michael McClain and K. M. Nicholas, Chem. Commun., 2016, 52, 7257 DOI: 10.1039/C6CC00537C
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