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Issue 30, 2016
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Full chirality transfer in the synthesis of hindered tertiary boronic esters under in situ lithiation–borylation conditions

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Abstract

Hindered tertiary neopentyl glycol boronic esters can be prepared by using in situ lithiation–borylation of enantiopure secondary benzylic carbamates at −20 °C with full chirality transfer.

Graphical abstract: Full chirality transfer in the synthesis of hindered tertiary boronic esters under in situ lithiation–borylation conditions

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Supplementary files

Article information


Submitted
19 Jan 2016
Accepted
14 Mar 2016
First published
22 Mar 2016

This article is Open Access

Chem. Commun., 2016,52, 5289-5292
Article type
Communication

Full chirality transfer in the synthesis of hindered tertiary boronic esters under in situ lithiation–borylation conditions

D. J. Blair, S. Zhong, M. J. Hesse, N. Zabaleta, E. L. Myers and V. K. Aggarwal, Chem. Commun., 2016, 52, 5289
DOI: 10.1039/C6CC00536E

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