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Issue 25, 2016
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Unraveling a two-step oxidation mechanism in electrochemical Cu-MOF synthesis

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Abstract

To employ the full potential of electrochemical (ec) synthesis to grow metal–organic frameworks (MOFs) in more complex organizations at the mesoscale, it is vital to understand the underlying crystallization reaction pathway. For the MOF most typically grown electrochemically, CuBTC, we systematically investigated the role of oxygen species in the synthesis.

Graphical abstract: Unraveling a two-step oxidation mechanism in electrochemical Cu-MOF synthesis

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Publication details

The article was received on 19 Jan 2016, accepted on 26 Feb 2016 and first published on 01 Mar 2016


Article type: Communication
DOI: 10.1039/C6CC00534A
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Chem. Commun., 2016,52, 4722-4725
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    Unraveling a two-step oxidation mechanism in electrochemical Cu-MOF synthesis

    P. Schäfer, M. A. van der Veen and K. F. Domke, Chem. Commun., 2016, 52, 4722
    DOI: 10.1039/C6CC00534A

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