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Issue 18, 2016
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Tuning of molecular qubits: very long coherence and spin–lattice relaxation times

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Abstract

We report a pulsed EPR study on different transition metal phthalocyanines, elucidating the dependence of spin relaxation on solvent, ligand and metal ion. Coherence times of >40 µs and spin–lattice relaxation times of up to 2 s were found. Minimization of SOMO-environment overlap leads to increased coherence times.

Graphical abstract: Tuning of molecular qubits: very long coherence and spin–lattice relaxation times

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Supplementary files

Article information


Submitted
12 Jan 2016
Accepted
03 Feb 2016
First published
03 Feb 2016

This article is Open Access

Chem. Commun., 2016,52, 3623-3626
Article type
Communication

Tuning of molecular qubits: very long coherence and spin–lattice relaxation times

K. Bader, M. Winkler and J. van Slageren, Chem. Commun., 2016, 52, 3623
DOI: 10.1039/C6CC00300A

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