Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents

Anton Peristyy; Pavel N. Nesterenko; Anita Das; Deanna M. D'Alessandro; Emily F. Hilder; R. Dario Arrua

doi:10.1039/C6CC00111D

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Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents†

Anton Peristyy,^a Pavel N. Nesterenko,^a Anita Das,^b Deanna M. D'Alessandro,^b Emily F. Hilder^a and R. Dario Arrua*^a

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* Corresponding authors

^a Australian Centre for Research on Separation Science, University of Tasmania, Private Bag 75, Hobart, TAS 7001, Australia
E-mail: Dario.Arrua@utas.edu.au, Dario.Arrua@unisa.edu.au

^b School of Chemistry F11, University of Sydney, NSW 2006, Australia

Abstract

A new flow-dependent separation selectivity (FDSS) effect was discovered in isocratic HPLC. Significant changes in chromatographic selectivity were achieved by simple variation of the mobile phase flow rate. The FDSS effect was observed for a core–shell stationary phase using silica particles as a core and a Zr-based metal–organic framework (UiO-66) as a shell.

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Article information

DOI: https://doi.org/10.1039/C6CC00111D
Article type: Communication
Submitted: 06 Jan 2016
Accepted: 18 Mar 2016
First published: 18 Mar 2016
This article is Open Access

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Chem. Commun., 2016,52, 5301-5304

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Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents

A. Peristyy, P. N. Nesterenko, A. Das, D. M. D'Alessandro, E. F. Hilder and R. D. Arrua, Chem. Commun., 2016, 52, 5301 DOI: 10.1039/C6CC00111D

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Chemical Communications

Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents†

Abstract

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Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents

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