Enhanced performance in gas adsorption and Li ion batteries by docking Li+ in a crown ether-based metal–organic framework

Linyi Bai; Binbin Tu; Yi Qi; Qiang Gao; Dong Liu; Zhizhou Liu; Lingzhi Zhao; Qiaowei Li; Yanli Zhao

doi:10.1039/C5CC09935H

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Enhanced performance in gas adsorption and Li ion batteries by docking Li⁺ in a crown ether-based metal–organic framework†

Linyi Bai,‡^a Binbin Tu,‡^b Yi Qi,^b Qiang Gao,^a Dong Liu,^a Zhizhou Liu,^a Lingzhi Zhao,^a Qiaowei Li*^b and Yanli Zhao*^ac

Author affiliations

* Corresponding authors

^a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371, Singapore
E-mail: zhaoyanli@ntu.edu.sg

^b Department of Chemistry and iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Fudan University, 220 Handan Road, Shanghai 200433, P. R. China
E-mail: qwli@fudan.edu.cn

^c School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore

Abstract

Incorporating supramolecular interaction units, crown ether rings, into metal–organic frameworks enables the docking of metal ions through complexation for enhanced performance in H₂ and CO₂ adsorption and lithium ion batteries.

This article is part of the themed collection: Host–guest chemistry

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Article information

DOI: https://doi.org/10.1039/C5CC09935H
Article type: Communication
Submitted: 02 Dec 2015
Accepted: 12 Jan 2016
First published: 12 Jan 2016

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Chem. Commun., 2016,52, 3003-3006

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Enhanced performance in gas adsorption and Li ion batteries by docking Li⁺ in a crown ether-based metal–organic framework

L. Bai, B. Tu, Y. Qi, Q. Gao, D. Liu, Z. Liu, L. Zhao, Q. Li and Y. Zhao, Chem. Commun., 2016, 52, 3003 DOI: 10.1039/C5CC09935H

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Chemical Communications