Issue 14, 2016

Cuprophilic interactions in highly luminescent dicopper(i)–NHC–picolyl complexes – fast phosphorescence or TADF?

Abstract

This case study on a series of monomeric, dimeric and polymeric CuI chlorido NHC–picolyl complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast (reverse)intersystem-crossing T1 ↔ S1 and T1 → S0, and therefore can serve as a design motif for the construction of highly efficient CuI-based TADF or T1 emitters.

Graphical abstract: Cuprophilic interactions in highly luminescent dicopper(i)–NHC–picolyl complexes – fast phosphorescence or TADF?

Supplementary files

Article information

Article type
Communication
Submitted
22 Nov 2015
Accepted
18 Dec 2015
First published
04 Jan 2016

Chem. Commun., 2016,52, 2932-2935

Cuprophilic interactions in highly luminescent dicopper(I)–NHC–picolyl complexes – fast phosphorescence or TADF?

J. Nitsch, F. Lacemon, A. Lorbach, A. Eichhorn, F. Cisnetti and A. Steffen, Chem. Commun., 2016, 52, 2932 DOI: 10.1039/C5CC09659F

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