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Issue 12, 2016
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Ferrocene-containing non-interlocked molecular machines

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Abstract

Ferrocene is the prototypical organometallic sandwich complex and despite over 60 years passing since the discovery and elucidation of ferrocene's structure, research into ferrocene-containing compounds continues to grow as potential new applications in catalysis, biology and the material sciences are found. Ferrocene is chemically robust and readily functionalized which enables its facile incorporation into more complex molecular systems. This coupled with ferrocene's reversible redox properties and ability function as a “molecular ball bearing” has led to the use of ferrocene as a component in wide range of interlocked and non-interlocked synthetic molecular machine systems. This review will focus on the exploitation of ferrocene (and related sandwich complexes) for the development of non-interlocked synthetic molecular machines.

Graphical abstract: Ferrocene-containing non-interlocked molecular machines

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Article information


Submitted
19 Nov 2015
Accepted
23 Dec 2015
First published
23 Dec 2015

Chem. Commun., 2016,52, 2451-2464
Article type
Feature Article
Author version available

Ferrocene-containing non-interlocked molecular machines

S. Ø. Scottwell and J. D. Crowley, Chem. Commun., 2016, 52, 2451
DOI: 10.1039/C5CC09569G

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