trans–cis Configuration regulated supramolecular polymer gels and chirality transfer based on a bolaamphiphilic histidine and dicarboxylic acids

Chunfeng Chen; Tianyu Wang; Yunzhi Fu; Minghua Liu

doi:10.1039/C5CC09210H

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trans–cis Configuration regulated supramolecular polymer gels and chirality transfer based on a bolaamphiphilic histidine and dicarboxylic acids†

Chunfeng Chen,^ab Tianyu Wang,*^b Yunzhi Fu^a and Minghua Liu*^bc

Author affiliations

* Corresponding authors

^a Department of Materials Science and Chemical Engineering, Hainan University, Haikou, P. R. China

^b Beijing National Laboratory for Molecular Science, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: liumh@iccas.ac.cn, twang@iccas.ac.cn
Tel: +86-10-8261-5803

^c Collaborative Innovation Center of Chemical Science and Engineering, Tianjin, P. R. China

Abstract

Supramolecular polymer gels based on the co-assembly of bolaamphiphilic L-histidine(BolaHis) and dicarboxylic acids are dependent on the molar ratios, flexibility and cis–trans configuration of acid molecules. Thus, oligomerized rigid cis-maleic acid or flexible trans-cyclohexane dicarboxylic acid can form chiral supramolecular polymer gels with L-BolaHis.

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Article information

DOI: https://doi.org/10.1039/C5CC09210H
Article type: Communication
Submitted: 06 Nov 2015
Accepted: 23 Nov 2015
First published: 23 Nov 2015

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Chem. Commun., 2016,52, 1381-1384

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trans–cis Configuration regulated supramolecular polymer gels and chirality transfer based on a bolaamphiphilic histidine and dicarboxylic acids

C. Chen, T. Wang, Y. Fu and M. Liu, Chem. Commun., 2016, 52, 1381 DOI: 10.1039/C5CC09210H

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Chemical Communications

trans–cis Configuration regulated supramolecular polymer gels and chirality transfer based on a bolaamphiphilic histidine and dicarboxylic acids†

Abstract

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trans–cis Configuration regulated supramolecular polymer gels and chirality transfer based on a bolaamphiphilic histidine and dicarboxylic acids

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