Issue 10, 2016

Synthesis and catalytic applications of C3-symmetric tris(triazolyl)methanol ligands and derivatives

Abstract

Recently introduced tris(1,2,3-triazol-4-yl)methanols and derivatives (TTM ligands) have become a valuable subclass of C3-symmetric tripodal ligands for transition metal-mediated reactions. TTM-based ligand architectures are modularly constructed through regioselective, one-pot triple [3+2] cycloaddition of azides and alkynes. Applications of homogeneous systems of this type and of heterogenised (polystyrene- and magnetic nanoparticle-supported) TTM ligands in synthesis and catalysis are compiled in this Feature Article.

Graphical abstract: Synthesis and catalytic applications of C3-symmetric tris(triazolyl)methanol ligands and derivatives

Article information

Article type
Feature Article
Submitted
28 Oct 2015
Accepted
16 Dec 2015
First published
16 Dec 2015

Chem. Commun., 2016,52, 1997-2010

Author version available

Synthesis and catalytic applications of C3-symmetric tris(triazolyl)methanol ligands and derivatives

P. Etayo, C. Ayats and M. A. Pericàs, Chem. Commun., 2016, 52, 1997 DOI: 10.1039/C5CC08961A

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