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Issue 11, 2016
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Synthesis, structure and reactivity of [TmBut]ZnH, a monomeric terminal zinc hydride compound in a sulfur-rich coordination environment: access to a heterobimetallic compound

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Abstract

The first terminal zinc hydride complex that features a sulfur-rich coordination environment, namely the tris(2-mercapto-1-tert-butylimidazolyl)hydroborato compound, [TmBut]ZnH, has been synthesized via the reaction of [TmBut]ZnOPh with PhSiH3. The Zn–H bond of [TmBut]ZnH is subject to insertion of CO2 and facile protolytic cleavage, of which the latter provides access to heterobimetallic [TmBut]ZnMo(CO)3Cp.

Graphical abstract: Synthesis, structure and reactivity of [TmBut]ZnH, a monomeric terminal zinc hydride compound in a sulfur-rich coordination environment: access to a heterobimetallic compound

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Article information


Submitted
27 Oct 2015
Accepted
27 Nov 2015
First published
05 Jan 2016

Chem. Commun., 2016,52, 2358-2361
Article type
Communication

Synthesis, structure and reactivity of [TmBut]ZnH, a monomeric terminal zinc hydride compound in a sulfur-rich coordination environment: access to a heterobimetallic compound

A. Kreider-Mueller, P. J. Quinlivan, M. Rauch, J. S. Owen and G. Parkin, Chem. Commun., 2016, 52, 2358
DOI: 10.1039/C5CC08915H

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