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Issue 12, 2016
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A one-pot synthesis of polysulfane-bearing block copolymer nanoparticles with tunable size and refractive index

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Abstract

A one-pot synthesis of sulfur-rich polymer nanoparticles through a ring-opening metathesis polymerization is reported. The nanoparticles are formed in situ from diblock copolymers containing a polynorbornene derivative bearing cyclic polysulfanes. The refractive indices of the resulting nanoparticles are readily controlled in the range from 1.54 to nearly 1.65.

Graphical abstract: A one-pot synthesis of polysulfane-bearing block copolymer nanoparticles with tunable size and refractive index

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Article information


Submitted
13 Oct 2015
Accepted
21 Nov 2015
First published
23 Nov 2015

Chem. Commun., 2016,52, 2485-2488
Article type
Communication

A one-pot synthesis of polysulfane-bearing block copolymer nanoparticles with tunable size and refractive index

J. Lim, Y. Cho, E. Kang, S. Yang, J. Pyun, T. Choi and K. Char, Chem. Commun., 2016, 52, 2485
DOI: 10.1039/C5CC08490C

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