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Issue 5, 2016
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Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters

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Abstract

We report the formation of two polyoxotungstates of the general formula [M6(PW6O26)(α-P2W15O56)2(H2O)2]23− (M = CoII or MnII), which contain {PW6} fragments generated from the [P2W15O56]12− precursor, which demonstrates for the first time the transformation of a Dawson lacunae into a Keggin lacunary building block. Solution analysis of the clusters has been conducted via electrospray ionisation mass spectrometry.

Graphical abstract: Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters

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Supplementary files

Article information


Submitted
13 Oct 2015
Accepted
06 Nov 2015
First published
09 Nov 2015

This article is Open Access

Chem. Commun., 2016,52, 919-921
Article type
Communication

Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters

M. Martin-Sabi, R. S. Winter, C. Lydon, J. M. Cameron, D. Long and L. Cronin, Chem. Commun., 2016, 52, 919
DOI: 10.1039/C5CC08486E

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