Issue 6, 2016

The first organically templated open-framework metal-sulfites with layered and three-dimensional diamondoid structures

Abstract

The crystallographic signatures and characterization data of two novel organically templated open-framework zinc-sulfites (NH3CH2CH2NH3)[Zn3(SO3)4], 1, and (CN3H6)2[Zn(SO3)2], 2, are reported for the first time, synthesized under hydrothermal conditions using different amines, namely, ethylenediamine and guanidine, to generate 2D (for 1) and 3D (for 2) assemblies with 4-, 6-, 8- and 12-membered rings.

Graphical abstract: The first organically templated open-framework metal-sulfites with layered and three-dimensional diamondoid structures

Supplementary files

Article information

Article type
Communication
Submitted
19 Sep 2015
Accepted
13 Nov 2015
First published
16 Nov 2015

Chem. Commun., 2016,52, 1282-1285

Author version available

The first organically templated open-framework metal-sulfites with layered and three-dimensional diamondoid structures

R. K. Tiwari, J. Kumar and J. N. Behera, Chem. Commun., 2016, 52, 1282 DOI: 10.1039/C5CC07874A

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