Strapped heterobimetallic Hg(II)/Tl(I) porphyrin complexes, with both metal ions bridged by the N-core in a dynamic way, undergo spontaneous Tl(I)-to-Tl(III) oxidation leading to a mono-Tl(III) complex and a mixed valence Tl(I)/Tl(III) bimetallic complex. It provides a new opportunity to tune metal ion translocations in bimetallic porphyrin systems.
V. Ndoyom, L. Fusaro, T. Roisnel, S. L. Gac and B. Boitrel, Chem. Commun., 2016, 52, 517 DOI: 10.1039/C5CC07828H
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