Silver(I)-mediated three-component annulation reaction of [60]fullerene, sulfonylhydrazones, and nitriles: leading to diverse disubstituted [60]fullerene-fused dihydropyrroles

Di Chao; Tong-Xin Liu; Nana Ma; Pengling Zhang; Zheng Fu; Jinliang Ma; Qingfeng Liu; Fengjin Zhang; Zhiguo Zhang; Guisheng Zhang

doi:10.1039/C5CC07218B

Silver(i)-mediated three-component annulation reaction of [60]fullerene, sulfonylhydrazones, and nitriles: leading to diverse disubstituted [60]fullerene-fused dihydropyrroles†

Di Chao,^a Tong-Xin Liu,*^a Nana Ma,^a Pengling Zhang,^a Zheng Fu,^a Jinliang Ma,^a Qingfeng Liu,^a Fengjin Zhang,^a Zhiguo Zhang^a and Guisheng Zhang*^a

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* Corresponding authors

^a Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, P. R. China
E-mail: liutongxin_0912@126.com, zgs6668@yahoo.com

Abstract

A novel Ag(I)-induced three-component annulation reaction of [60]fullerene with sulfonylhydrazones and nitriles has been developed for the efficient synthesis of diverse disubstituted [60]fullerene-fused dihydropyrroles. The reaction exhibits a broad substrate scope and excellent functional-group tolerance, and also allows for the synthesis of fullerene-bound macromolecules.

Chemical Communications

Silver(i)-mediated three-component annulation reaction of [60]fullerene, sulfonylhydrazones, and nitriles: leading to diverse disubstituted [60]fullerene-fused dihydropyrroles†

Abstract

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Silver(I)-mediated three-component annulation reaction of [60]fullerene, sulfonylhydrazones, and nitriles: leading to diverse disubstituted [60]fullerene-fused dihydropyrroles

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