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Issue 19, 2016
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A conditioning-free magnesium chloride complex electrolyte for rechargeable magnesium batteries

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Abstract

The dissolution of Mg metal in AlCl3/THF using CrCl3 as a “promoter” yields a magnesium aluminum chloride complex electrolyte which shares many common features with MACC, but does not require an onerous conditioning process. This crucial advantage originates from the very high Mg to Al ratio in the new electrolyte, “MaCC”, which promotes 100% coulombic efficiency for Mg in the first cycle.

Graphical abstract: A conditioning-free magnesium chloride complex electrolyte for rechargeable magnesium batteries

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Article information


Submitted
25 Feb 2016
Accepted
12 Apr 2016
First published
12 Apr 2016

J. Mater. Chem. A, 2016,4, 7160-7164
Article type
Communication
Author version available

A conditioning-free magnesium chloride complex electrolyte for rechargeable magnesium batteries

J. H. Ha, B. Adams, J. Cho, V. Duffort, J. H. Kim, K. Y. Chung, B. W. Cho, L. F. Nazar and S. H. Oh, J. Mater. Chem. A, 2016, 4, 7160
DOI: 10.1039/C6TA01684G

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