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Issue 23, 2016
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Wettability of PEDOT:PSS films

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Abstract

Conducting polymers such as poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) are increasingly used to interface electronics with biology. Their wettability, however, remains poorly understood. We show that the frequently-used sessile drop technique yields results that are strongly dependent on the experimental conditions (measurement duration and relative humidity), due to the hydrogel-like behavior of PEDOT:PSS. In contrast, the captive bubble technique on a fully wet film overcomes these limitations. Dynamic wettability measurements provide hysteresis values for this polymer and clarify the physical meaning of the static contact angles measured by sessile drop and captive bubble. Finally we show that aging the films in water leads to loss of PSS chains which makes the films more hydrophobic. The addition of a crosslinker reduces and slows down these effects.

Graphical abstract: Wettability of PEDOT:PSS films

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Supplementary files

Article information


Submitted
09 Mar 2016
Accepted
03 May 2016
First published
03 May 2016

Soft Matter, 2016,12, 5146-5153
Article type
Paper

Wettability of PEDOT:PSS films

C. Duc, A. Vlandas, G. G. Malliaras and V. Senez, Soft Matter, 2016, 12, 5146
DOI: 10.1039/C6SM00599C

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