Overall water splitting by Pt/g-C3N4 photocatalysts without using sacrificial agents†
We report the direct splitting of pure water by light-excited graphitic carbon nitride (g-C3N4) modified with Pt, PtOx, and CoOx as redox cocatalysts, while pure g-C3N4 is virtually inactive for overall water splitting by photocatalysis. The novelty is in the selective creation of both H2 and O2 cocatalysts on surface active sites of g-C3N4via photodeposition triggering the splitting of water for the simultaneous evolution of H2 and O2 gases in a stoichiometric ratio of 2 : 1, irradiated with light, without using any sacrificial reagents. The photocatalyst was stable for 510 hours of reaction.
- This article is part of the themed collections: In celebration of Kazunari Domen’s 65th birthday, 2018, Global Energy Challenges: Hydrogen Energy, Top 50 Articles of 2016: Energy and Catalysis and Top 50 Articles of 2016: Physical Chemistry