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Issue 109, 2016, Issue in Progress
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Copper-catalyzed carbonylation of anilines by diisopropyl azodicarboxylate for the synthesis of carbamates

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Abstract

A Cu-catalyzed efficient methodology for the direct carbonylation of anilines has been developed. The N–H bond cleavage and N–C bond formation were notably achieved under solvent-free conditions and a variety of carbamates were synthesized from readily available anilines using diisopropyl azodicarboxylate (DIAD) as the carbonylating source.

Graphical abstract: Copper-catalyzed carbonylation of anilines by diisopropyl azodicarboxylate for the synthesis of carbamates

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Publication details

The article was received on 03 Sep 2016, accepted on 27 Oct 2016 and first published on 27 Oct 2016


Article type: Communication
DOI: 10.1039/C6RA22108D
RSC Adv., 2016,6, 107542-107546

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    Copper-catalyzed carbonylation of anilines by diisopropyl azodicarboxylate for the synthesis of carbamates

    M. Usman, Z. Ren, Y. Wang and Z. Guan, RSC Adv., 2016, 6, 107542
    DOI: 10.1039/C6RA22108D

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