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Issue 99, 2016
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Visible light-mediated decarboxylative amination of indoline-2-carboxylic acids catalyzed by Rose Bengal

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Abstract

A visible light-induced decarboxylative amination of indoline-2-carboxylic acids and azodicarboxylate esters has been developed, in which the oxidation of α-amino acids provides a versatile CO2-extrusion platform to generate α-aminoalkyl radicals. The corresponding products were obtained with yields of up to 72% catalyzed by a metal-free photocatalyst under mild conditions.

Graphical abstract: Visible light-mediated decarboxylative amination of indoline-2-carboxylic acids catalyzed by Rose Bengal

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Supplementary files

Article information


Submitted
08 Jul 2016
Accepted
07 Oct 2016
First published
07 Oct 2016

RSC Adv., 2016,6, 96693-96699
Article type
Paper

Visible light-mediated decarboxylative amination of indoline-2-carboxylic acids catalyzed by Rose Bengal

M. Zhang, G. M. Schroeder, Y. He and Z. Guan, RSC Adv., 2016, 6, 96693
DOI: 10.1039/C6RA17524D

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