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Issue 85, 2016, Issue in Progress
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Synthesis and solid-state fluorescence of aryl substituted 2-halogenocinchomeronic dinitriles

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Abstract

Based on the reaction of available adducts of tetracyanoethylene (TCNE) and aromatic ketones (4-aryl-4-oxoalkane-1,1,2,2-tetracarbonitriles) with hydrogen chloride, several aryl substituted 2-halogencinchomeronic dinitriles were synthesized. We found that aryl substituted derivatives, in contrast to alkyl substituted ones, possess an intensive solid state fluorescence. The relationship between the chemical structures and photophysical properties of these compounds was investigated.

Graphical abstract: Synthesis and solid-state fluorescence of aryl substituted 2-halogenocinchomeronic dinitriles

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Article information


Submitted
29 Jun 2016
Accepted
12 Aug 2016
First published
15 Aug 2016

RSC Adv., 2016,6, 82227-82232
Article type
Paper

Synthesis and solid-state fluorescence of aryl substituted 2-halogenocinchomeronic dinitriles

O. V. Ershov, M. Yu. Ievlev, M. Yu. Belikov, K. V. Lipin, A. I. Naydenova and V. A. Tafeenko, RSC Adv., 2016, 6, 82227
DOI: 10.1039/C6RA16787J

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