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Issue 83, 2016
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Microperoxidase-11/metal–organic framework/macroporous carbon for detecting hydrogen peroxide

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Abstract

In this work, a novel hydrogen peroxide (H2O2) electrochemical biosensor was developed based on the metal–organic framework (MOF, Tb@mesoMOF) modified three-dimensional (3D) kenaf stem-derived macroporous carbon (3D-KSCs) electrode which was used as a new platform to load microperoxidase-11 (MP-11) for the first time. The chitosan-Au nanoparticles (CHIT-AuNPs) were firstly electrodeposited on the 3D-KSCs integrated electrode, which provided a large number of active sites for the growth of Tb@mesoMOFs to form the Tb@mesoMOFs/CHIT-AuNPs/3D-KSCs integrated electrode. Then the MP-11 molecules were effectively encapsulated in Tb@mesoMOFs of the Tb@mesoMOFs/CHIT-AuNPs/3D-KSCs integrated electrode. Scanning electron microscopy and energy disperse X-ray spectroscopy was used to characterize the resulting electrode. The results showed that a large number of spherical Tb@mesoMOFs grew on the CHIT-AuNPs/3D-KSCs electrode uniformly and firmly. The electrochemical performance of the MP-11/Tb@mesoMOFs/CHIT-AuNPs/3D-KSCs electrode were also explored. The resulting MP-11/Tb@mesoMOFs/CHIT-AuNPs/3D-KSCs integrated electrode showed good performance toward the detection of H2O2 with a wide linear range from 3.02 μM to 640 μM and a low detection limit of 0.996 μM. This work provides new ideas to design MOFs/3D-KSCs integrated electrodes for enzyme immobilization to construct electrochemical biosensors.

Graphical abstract: Microperoxidase-11/metal–organic framework/macroporous carbon for detecting hydrogen peroxide

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Publication details

The article was received on 22 Jun 2016, accepted on 04 Aug 2016 and first published on 16 Aug 2016


Article type: Paper
DOI: 10.1039/C6RA16145F
RSC Adv., 2016,6, 79798-79804

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    Microperoxidase-11/metal–organic framework/macroporous carbon for detecting hydrogen peroxide

    C. Gong, J. Chen, Y. Shen, Y. Song, Y. Song and L. Wang, RSC Adv., 2016, 6, 79798
    DOI: 10.1039/C6RA16145F

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