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Issue 10, 2016
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Switching between intermolecular and intramolecular reactions using flow microreactors: lithiation of 2-bromo-2′-silylbiphenyls

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Abstract

Reaction-pathway control of 2-lithio-2′-silylbiphenyls was accomplished in flow microreactor systems. Effective switching between the intermolecular reaction with an electrophile and the intramolecular reaction was performed at will by choosing an appropriate residence time and temperature region.

Graphical abstract: Switching between intermolecular and intramolecular reactions using flow microreactors: lithiation of 2-bromo-2′-silylbiphenyls

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Publication details

The article was received on 09 Jun 2016, accepted on 25 Jul 2016 and first published on 26 Jul 2016


Article type: Research Article
DOI: 10.1039/C6QO00257A
Org. Chem. Front., 2016,3, 1250-1253

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    Switching between intermolecular and intramolecular reactions using flow microreactors: lithiation of 2-bromo-2′-silylbiphenyls

    A. Nagaki, S. Kim, N. Miuchi, H. Yamashita, K. Hirose and J. Yoshida, Org. Chem. Front., 2016, 3, 1250
    DOI: 10.1039/C6QO00257A

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