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Issue 12, 2016
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Phototriggered supramolecular polymerization of a [c2]daisy chain rotaxane

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Abstract

A new strategy for phototriggered supramolecular polymerization of the [c2]daisy chain is demonstrated. A daisy chain rotaxane containing two coumarin protected 2-ureido-4-pyrimidinone (Upy) terminals at two ends was designed, whose supramolecular polymerization can be initiated by light irradiation that can remove the photocleavable protecting coumarin groups and uncage the two terminal Upy functional units.

Graphical abstract: Phototriggered supramolecular polymerization of a [c2]daisy chain rotaxane

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Article information


Submitted
18 Feb 2016
Accepted
24 Feb 2016
First published
25 Feb 2016

Polym. Chem., 2016,7, 2166-2170
Article type
Communication

Phototriggered supramolecular polymerization of a [c2]daisy chain rotaxane

X. Fu, R. Gu, Q. Zhang, S. Rao, X. Zheng, D. Qu and H. Tian, Polym. Chem., 2016, 7, 2166
DOI: 10.1039/C6PY00309E

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