Issue 37, 2016
From the journal:

Polymer Chemistry

Ligand effects on cooperative supramolecular polymerization of platinum(ii) acetylide complexes†

Zhao Gao,a   Junlong Zhu,a   Yifei Han,a   Xiaoqin Lv,a   Xiaolong Zhanga  and  Feng Wang*a  

* Corresponding authors

a CAS Key Laboratory of Soft Matter Chemistry, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China
E-mail: drfwang@ustc.edu.cn

Abstract

A rod-like platinum(II) acetylide monomer with a less bulky ligand is prone to form helical nanofibers and organogels via a cooperative nucleation–elongation mechanism, whilst no aggregation can be detected for the bulky counterpart, thus demonstrating the significant role of ligand effects on the macroscopic supramolecular polymerization behaviors.

Graphical abstract: Ligand effects on cooperative supramolecular polymerization of platinum(ii) acetylide complexes

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Article information

DOI
https://doi.org/10.1039/C6PY01440B
Article type
Communication
Submitted
18 Aug 2016
Accepted
30 Aug 2016
First published
31 Aug 2016

Polym. Chem., 2016,7, 5763-5767

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Ligand effects on cooperative supramolecular polymerization of platinum(II) acetylide complexes

Z. Gao, J. Zhu, Y. Han, X. Lv, X. Zhang and F. Wang, Polym. Chem., 2016, 7, 5763 DOI: 10.1039/C6PY01440B

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