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Issue 39, 2016
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Total synthesis of haliclamide

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A stereoselective approach for the synthesis of haliclamide 1, a marine natural product, has been developed. The notable features of our synthesis include MacMillan cross aldol, Mitsunobu inversion, Yamaguchi–Hirao alkylation, Steglich esterification and macrolactamization reactions and the Corey–Fuchs protocol as the key steps.

Graphical abstract: Total synthesis of haliclamide

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The article was received on 15 Aug 2016, accepted on 02 Sep 2016 and first published on 02 Sep 2016

Article type: Paper
DOI: 10.1039/C6OB01775D
Org. Biomol. Chem., 2016,14, 9287-9293

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    Total synthesis of haliclamide

    S. Gahalawat and S. K. Pandey, Org. Biomol. Chem., 2016, 14, 9287
    DOI: 10.1039/C6OB01775D

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