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Issue 23, 2016
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Studies towards the synthesis of tedanolide C. Construction of the C13-epi C1–C15 fragment

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Abstract

The preparation of an advanced intermediate on route towards the synthesis of tedanolide C is reported here. It is based on the coupling of two fragments of similar size and complexity, which in turn are prepared by highly stereoselective substrate-controlled titanium-mediated aldol reactions from chiral ketones.

Graphical abstract: Studies towards the synthesis of tedanolide C. Construction of the C13-epi C1–C15 fragment

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Article information


Submitted
26 Apr 2016
Accepted
17 May 2016
First published
17 May 2016

Org. Biomol. Chem., 2016,14, 5219-5223
Article type
Communication

Studies towards the synthesis of tedanolide C. Construction of the C13-epi C1–C15 fragment

J. Zambrana, P. Romea and F. Urpí, Org. Biomol. Chem., 2016, 14, 5219
DOI: 10.1039/C6OB00896H

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