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Issue 19, 2016
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Efficient access to cis-decalinol frameworks: copper(i)-catalyzed borylative cyclization of allene cyclohexanediones

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Abstract

Cu-catalyzed borylative cyclization of allene cyclohexanediones has been described through a tandem β-borylation and intramolecular allylic addition process, affording borylated cis-decalinols with excellent yields and diastereoselectivities. A good enantioselectivity is also achieved in the asymmetric version. The hemiboronate group in the cyclization products could be subjected to several useful transformations.

Graphical abstract: Efficient access to cis-decalinol frameworks: copper(i)-catalyzed borylative cyclization of allene cyclohexanediones

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Article information


Submitted
15 Apr 2016
Accepted
21 Apr 2016
First published
21 Apr 2016

Org. Biomol. Chem., 2016,14, 4400-4404
Article type
Communication

Efficient access to cis-decalinol frameworks: copper(I)-catalyzed borylative cyclization of allene cyclohexanediones

Y. Zhao, X. Tang, J. Tao, P. Tian and G. Lin, Org. Biomol. Chem., 2016, 14, 4400
DOI: 10.1039/C6OB00804F

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