Issue 15, 2016
From the journal:

Organic & Biomolecular Chemistry

Two phenyls are better than one or three: synthesis and application of terminal olefin-oxazoline (TOlefOx) ligands†

Yi-Shuang Zhao,‡ab   Jian-Kang Liu,‡b   Zhi-Tao He,b   Jing-Chao Tao,*a   Ping Tian*bc  and  Guo-Qiang Linbc  

* Corresponding authors

a College of Chemistry and Molecular Engineering, Zhengzhou University, 75 Daxue Road, Zhengzhou, Henan 450052, China
Tel: +86-371-67767200

b CAS Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China
E-mail: tianping@sioc.ac.cn
Tel: +86-21-54925081

c Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China

Abstract

A novel terminal olefin-oxazoline ligand was introduced into rhodium-catalyzed asymmetric conjugate addition of arylboronic acids to enones and gave excellent enantioselectivities. The two phenyls proved better than one or three in ligand evaluations.

Graphical abstract: Two phenyls are better than one or three: synthesis and application of terminal olefin-oxazoline (TOlefOx) ligands

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Article information

DOI
https://doi.org/10.1039/C6OB00460A
Article type
Communication
Submitted
29 Feb 2016
Accepted
17 Mar 2016
First published
17 Mar 2016

Org. Biomol. Chem., 2016,14, 3686-3689

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Two phenyls are better than one or three: synthesis and application of terminal olefin-oxazoline (TOlefOx) ligands

Y. Zhao, J. Liu, Z. He, J. Tao, P. Tian and G. Lin, Org. Biomol. Chem., 2016, 14, 3686 DOI: 10.1039/C6OB00460A

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