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Issue 16, 2016
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A combined computational and experimental investigation of the oxidative ring-opening of cyclic ethers by oxoammonium cations

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Abstract

The propensity of oxoammonium cations to facilitate the oxidative ring-opening of cyclic ethers to their corresponding distal hydroxy ketones is investigated. The reaction has been evaluated using experimental and computational methods to gain deeper insight into trends in reactivity.

Graphical abstract: A combined computational and experimental investigation of the oxidative ring-opening of cyclic ethers by oxoammonium cations

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Supplementary files

Article information


Submitted
12 Feb 2016
Accepted
18 Mar 2016
First published
18 Mar 2016

Org. Biomol. Chem., 2016,14, 3883-3888
Article type
Paper

A combined computational and experimental investigation of the oxidative ring-opening of cyclic ethers by oxoammonium cations

Jacob. J. Loman, E. R. Carnaghan, T. A. Hamlin, J. M. Ovian, C. B. Kelly, M. A. Mercadante and N. E. Leadbeater, Org. Biomol. Chem., 2016, 14, 3883
DOI: 10.1039/C6OB00347H

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