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Issue 1, 2016
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Efficient, versatile and practical palladium-catalyzed highly regioselective ortho-halogenation of azoxybenzenes

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Abstract

A highly efficient and practical strategy for regio-selective ortho-halogenation (I, Br, Cl) of azoxybenzenes with NXS in the presence of palladium catalysts has been developed in good to excellent yields. The reaction proceeds smoothly and can tolerate a variety of functional groups. Moreover, this chemistry can be applied to substrates in at least a gram scale.

Graphical abstract: Efficient, versatile and practical palladium-catalyzed highly regioselective ortho-halogenation of azoxybenzenes

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Publication details

The article was received on 19 Oct 2015, accepted on 04 Nov 2015 and first published on 06 Nov 2015


Article type: Paper
DOI: 10.1039/C5OB02153G
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Org. Biomol. Chem., 2016,14, 323-329

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    Efficient, versatile and practical palladium-catalyzed highly regioselective ortho-halogenation of azoxybenzenes

    M. Sun, X. Chen, L. Zhang, W. Sun, Z. Wang, P. Guo, Y. Li and X. Yang, Org. Biomol. Chem., 2016, 14, 323
    DOI: 10.1039/C5OB02153G

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