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Issue 1, 2016
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Rhodium(iii)-catalyzed C–C coupling of 7-azaindoles with vinyl acetates and allyl acetates

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Abstract

The behaviour of electron-rich alkenes with 7-azaindoles in rhodium(III)-catalyzed C–H activation is investigated. Various substituted vinyl acetates and allyl acetates as coupling partners reacted smoothly providing a wide variety of 7-azaindole derivatives, and the selectivity of the coupling reaction is alkene-dependent. In addition, the approaches of rhodium(III)-catalyzed dehydrogenative Heck-type reaction (DHR) and carbonylation reaction were quite novel and simple.

Graphical abstract: Rhodium(iii)-catalyzed C–C coupling of 7-azaindoles with vinyl acetates and allyl acetates

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Article information


Submitted
09 Oct 2015
Accepted
02 Nov 2015
First published
04 Nov 2015

Org. Biomol. Chem., 2016,14, 229-237
Article type
Paper
Author version available

Rhodium(III)-catalyzed C–C coupling of 7-azaindoles with vinyl acetates and allyl acetates

S. Li, C. Wang, H. Lin, X. Zhang and L. Dong, Org. Biomol. Chem., 2016, 14, 229
DOI: 10.1039/C5OB02096D

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