Jump to main content
Jump to site search

Issue 10, 2016
Previous Article Next Article

AuNp@MOF composite as electrochemical material for determination of bisphenol A and its oxidation behavior study

Author affiliations

Abstract

A composite material based on a metal organic framework (MOF), nanowhisker of Al2O3 silanized with (3-aminopropyl)triethoxysilane (APTES) and gold nanoparticles (AuNp) was synthesized and characterized. This material was used to prepare an electrode based in carbon paste (CPE) and applied as a sensor for the determination of bisphenol A (BPA). The electrochemical characterizations and behaviour of the electrode containing the AuNp@MOF composite exhibited a 2.3 higher electroactive surface area, when compared with just CPE. Using differential pulse voltammetry (DPV), it can be noted that the presence of AuNp plays an important role in enhancing the analyte signal detection of BPA 2.5-fold. A linear increase in emphasizing the response as a function of analyte concentration is demonstrated. In this account, we believe that this composite may be applied in analyticals methods for the determination of BPA and others endocrine disruptors.

Graphical abstract: AuNp@MOF composite as electrochemical material for determination of bisphenol A and its oxidation behavior study

Back to tab navigation

Supplementary files

Article information


Submitted
24 Mar 2016
Accepted
31 Aug 2016
First published
31 Aug 2016

New J. Chem., 2016,40, 8872-8877
Article type
Paper

AuNp@MOF composite as electrochemical material for determination of bisphenol A and its oxidation behavior study

C. T. P. da Silva, F. R. Veregue, L. W. Aguiar, J. G. Meneguin, M. P. Moisés, S. L. Fávaro, E. Radovanovic, E. M. Girotto and A. W. Rinaldi, New J. Chem., 2016, 40, 8872
DOI: 10.1039/C6NJ00936K

Social activity

Search articles by author

Spotlight

Advertisements