Jump to main content
Jump to site search

Issue 18, 2016
Previous Article Next Article

An integrated electrochemical process to convert lignin to value-added products under mild conditions

Author affiliations

Abstract

The controlled depolymerization of lignin is a promising approach for the generation of value-added compounds from biomass. And even though many different technologies to this end have been developed in the past, most of them require elevated temperatures and pressures to realize the depolymerization. In contrast, the electrochemical depolymerization of lignin can be achieved at ambient pressure and room temperature. However, as electrochemical processes are predominantly surface-catalyzed, the influence of the electrode structure plays a major role with regard to the process effectivity. In addition, the unselective mechanism of the electrochemical process reduces product yield by overoxidizing products. We report the use of 3D-structured electrode materials for the electrochemical depolymerization of lignin with a subsequent membrane filtration in order to increase product yield. The complete depolymerization of lignin at room temperature and ambient pressure to monomeric products could be achieved in less than four hours, with the successful continuous separation of monomers and residual lignin.

Graphical abstract: An integrated electrochemical process to convert lignin to value-added products under mild conditions

Back to tab navigation

Supplementary files

Article information


Submitted
28 Mar 2016
Accepted
02 May 2016
First published
27 May 2016

Green Chem., 2016,18, 4999-5007
Article type
Paper

An integrated electrochemical process to convert lignin to value-added products under mild conditions

S. Stiefel, A. Schmitz, J. Peters, D. Di Marino and M. Wessling, Green Chem., 2016, 18, 4999
DOI: 10.1039/C6GC00878J

Social activity

Search articles by author

Spotlight

Advertisements