Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.

Issue 10, 2016
Previous Article Next Article

A dual-metal–organic-framework derived electrocatalyst for oxygen reduction

Author affiliations


High-performance electrocatalysts for the oxygen reduction reaction are indispensable in many electrochemical energy storage and conversion technologies. However, the lack of efficient and inexpensive catalysts or catalyst systems that can compete with noble metal catalysts hinders their large-scale industrial applications. As an important class of porous materials, metal–organic frameworks (MOFs) with systematically tailored structures and compositions have recently been suggested as promising precursors for the preparation of diverse functional materials. Here we report a dual-MOF confined-pyrolysis approach for the preparation of iron carbide nanoparticle-embedded carbon nanotube assemblies. Starting from a novel MOF-in-MOF precursor consisting of a Zn-based MOF polyhedron host and many engulfed Fe-based MOF nanorods, a complex structured composite material constructed from iron carbide nanocrystallite-embedded carbon nanotubes encapsulated in a porous carbon matrix is successfully prepared. We further demonstrate that the as-derived composite material manifests remarkable electrocatalytic performance for the oxygen reduction reaction in an alkaline electrolyte. The present strategy significantly expands the toolbox for the design and synthesis of MOF-derived functional materials for a wide range of applications.

Graphical abstract: A dual-metal–organic-framework derived electrocatalyst for oxygen reduction

Back to tab navigation

Supplementary files

Article information

27 Jul 2016
31 Aug 2016
First published
31 Aug 2016

Energy Environ. Sci., 2016,9, 3092-3096
Article type

A dual-metal–organic-framework derived electrocatalyst for oxygen reduction

B. Y. Guan, L. Yu and X. W. (David) Lou, Energy Environ. Sci., 2016, 9, 3092
DOI: 10.1039/C6EE02171A

Social activity

Search articles by author