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Issue 3, 2016
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The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteries

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Abstract

The energy density delivered by a Li-ion battery is a key parameter that needs to be significantly increased to address the global question of energy storage for the next 40 years. This quantity is directly proportional to the battery voltage (V) and the battery capacity (C) which are difficult to improve simultaneously when materials exhibit classical cationic redox activity. Recently, a cumulative cationic (M4+/M5+) and anionic (2O2−/(O2)n) redox activity has been demonstrated in the Li-rich Li2MO3 family of compounds, therefore enabling doubling of the energy density with respect to high-potential cathodes such as transition metal phosphates and sulfates. This paper aims to clarify the origin of this extra capacity by addressing some fundamental questions regarding reversible anionic redox in high-potential electrodes for Li-ion batteries. First, the ability of the system to stabilize the oxygen holes generated by Li-removal and to achieve a reversible oxo- to peroxo-like (2O2−/(O2)n) transformation is elucidated by means of a metal-driven reductive coupling mechanism. The penchant of the system for undergoing this reversible anionic redox or releasing O2 gas is then discussed with regards to experimental results for 3d- and 4d-based Li2MO3 phases. Finally, robust indicators are built as tools to predict which materials in the Li-rich TM-oxide family will undergo efficient and reversible anionic redox. The present finding provides insights into new directions to be explored for the development of high-energy density materials for Li-ion batteries.

Graphical abstract: The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteries

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Supplementary files

Article information


Submitted
06 Oct 2015
Accepted
27 Oct 2015
First published
30 Oct 2015

Energy Environ. Sci., 2016,9, 984-991
Article type
Paper
Author version available

The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteries

M. Saubanère, E. McCalla, J.-M. Tarascon and M.-L. Doublet, Energy Environ. Sci., 2016, 9, 984
DOI: 10.1039/C5EE03048J

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